Speaker
Khristine Haydukivska
(Institute for Condensed Matter Physics NAS Ukraine)
Description
In the present work we calculated size characteristics of periodic hyperbranched polymers in dilute solution in the vicinity of the $\theta$ point using the continuous chain model. This model in its Gaussian approximation allows to receive exact solutions. Both the gyration radius and the hydrodynamic radius were calculated for the bottle-brush polymer and a tree-like one. We considered the size ratios $\rho=\frac{\sqrt{\langle R_g^2\rangle}}{\langle R_h\rangle}$ and $g = \frac{\langle R_{g}^2\rangle}{\langle R_{g,chain}^2\rangle}$, that allows to describe the characteristic sizes of this topologies. This types of ratios allow to shed some light on visco-elastic properties of polymer solutions.
Primary author
Khristine Haydukivska
(Institute for Condensed Matter Physics NAS Ukraine)
Co-author
Dr
Viktoria Blavatsks
(Institute for Condensed Matter Physics NAS Ukraine)